Nano Biomedicine
ORIGINAL ARTICLE

Improvement of Photocatalytic Activity of TiO2 Coating by the Modified Sol-gel Method

Mayuko AWATA1, Masahiro OKADA2, Takayuki NAMBU3 and Naoyuki MATSUMOTO4
1Graduate School of Dentistry (Department of Orthodontics),
Osaka Dental University, Osaka, Japan
2Department of Biomaterials, Graduate School of Medicine,
Dentistry and Pharmaceutical Sciences, Okayama University, Okayama, Japan
3Department of Bacteriology, 4Department of Orthodontics,
Osaka Dental University, Osaka, Japan


Nano Biomed 2015;7(2): 51-62, (Dec 30, Nano Biomedicine)

Synopsis
Photocatalytic TiO2 was coated on a stainless steel (SUS316L) substrate via a sol-gel method at a calcination temperature of 600°C. The sol-gel precursor (titanium isopropoxide) solution was modified by adding crystalline (anatase or rutile) TiO2 particles to control the crystal phase of the TiO2 coated on the substrate. The effect of the number of TiO2 coatings was also evaluated. The TiO2 coating was characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The photocatalytic activity was evaluated from the degradation of methylene blue solution on the TiO2 coating after UV irradiation. The amount of bacteria adhered on the substrate was also evaluated. The TiO2 coating comprising a binary phase (anatase/rutile weight ratio = 4.9/5.1) showed the highest photocatalytic activity, which improved after increasing the number of coatings. The amount of bacteria adhered on each TiO2-coated substrate was not sig-nificantly different from that on the uncoated substrate.

Key words: photocatalytic activity; TiO2; anatase; rutile; sol-gel method

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